Potassium Borohydride

    • Product Name: Potassium Borohydride
    • Chemical Name (IUPAC): Potassium tetrahydridoborate
    • CAS No.: 13762-51-1
    • Chemical Formula: KBH4
    • Form/Physical State: Powder Solid
    • Factroy Site: No.30 Fuduihe Road, Xuwei New District, Lianyungang, Jiangsu, China
    • Price Inquiry: sales3@ascent-petrochem.com
    • Manufacturer: Lianyungang Petrochemical Co., Ltd
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    Specifications

    HS Code

    263303

    Chemical Name Potassium Borohydride
    Chemical Formula KBH4
    Molecular Weight 53.94 g/mol
    Appearance White crystalline powder
    Melting Point 350 °C (decomposes)
    Density 1.18 g/cm³
    Solubility In Water 13.3 g/100 mL (cold)
    Cas Number 13762-51-1
    Odor Odorless
    Stability Stable under dry, inert atmosphere
    Reactivity Reacts with water to liberate hydrogen gas
    Storage Conditions Store in a cool, dry place; keep container tightly closed
    Ph Basic when dissolved in water

    As an accredited Potassium Borohydride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Application of Potassium Borohydride

    Purity 98%: Potassium Borohydride with 98% purity is used in the pharmaceutical industry for chemoselective reduction reactions, where it ensures high product yield and minimizes side reactions.

    Molecular Weight 53.94 g/mol: Potassium Borohydride with a molecular weight of 53.94 g/mol is used in organic synthesis, where it provides predictable stoichiometry for hydride transfer processes.

    Particle Size < 50 μm: Potassium Borohydride with particle size less than 50 μm is used in fine chemical manufacturing, where it offers fast and complete dissolution rates for efficient reduction reactions.

    Stability Temperature up to 100°C: Potassium Borohydride with stability temperature up to 100°C is used in polymer production processes, where it maintains reactivity and safety in moderate thermal environments.

    Water-Soluble Grade: Potassium Borohydride of water-soluble grade is used in aqueous analytical chemistry applications, where it provides reliable reduction of metal ions without precipitation issues.

    Low Impurity Content < 0.1%: Potassium Borohydride with impurity content less than 0.1% is used in electronics material synthesis, where it prevents contamination and ensures the purity of end products.

    Reagent Grade: Potassium Borohydride of reagent grade is used in academic research laboratories, where it guarantees consistent and reproducible experimental outcomes.

    Packing & Storage
    Packing Potassium Borohydride is supplied in a tightly sealed, 500g amber glass bottle with a tamper-evident cap, labeled with hazard warnings.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Potassium Borohydride: Packed securely in sealed drums, total load 12-14 metric tons per 20-foot container.
    Shipping Potassium borohydride is shipped in tightly sealed containers under dry, inert conditions to prevent moisture contact. It is classified as a hazardous material and must comply with local and international regulations for dangerous goods. Appropriate labeling, protective packaging, and documentation are required to ensure safe transport and handling.
    Storage Potassium borohydride should be stored in a tightly sealed container under an inert atmosphere, such as nitrogen or argon, to prevent reaction with moisture and air. Store it in a cool, dry, and well-ventilated area away from acids, water, and oxidizing agents. It should be kept away from sources of ignition, as it is a strong reducing agent and can react violently with water.
    Shelf Life Potassium borohydride typically has a shelf life of 2–3 years when stored in tightly sealed containers under dry, cool conditions.
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    More Introduction

    Potassium Borohydride: Practical Value in Modern Manufacturing

    A Reliable Hydride Reducing Agent

    Potassium borohydride stands out in our product line for its balance of performance and reliability. As a chemical manufacturer with decades of hands-on experience, we have seen this compound answer the call in tough industrial conditions. Its formula, KBH4, may appear simple, but that belies its versatility in reduction applications. In the shop floor, at pilot scale, or tucked inside a full-scale synthesis plant, it repeatedly proves its worth where other options either fail or create new headaches for the production crew.

    We produce potassium borohydride at a consistently high purity—ensuring less than 0.1% moisture content and negligible trace sodium—which directly correlates to fewer batch-to-batch surprises and higher yields for our partners. In our facility, every lot’s analysis matters, since even subtle impurities like heavy metals can disrupt downstream processes at the most inconvenient moments.

    The Role Potassium Borohydride Plays in Synthesis

    Chemists in the lab and engineers in plant operations trust potassium borohydride to tackle reduction steps that would otherwise pose safety risks or run up costs. We've seen it perform smoothly in the reduction of aldehydes and ketones, where its selectivity and gentle nature keep over-reduction at bay. In industrial settings, users often appreciate its lower reactivity toward esters and carboxylic acids, lending control over transformations that could easily spiral out with stronger hydrides.

    In our manufacturing experience, potassium borohydride carries several advantages over sodium borohydride for certain processes. The potassium ion offers higher solubility in some polar solvents, which translates into easier formulation for applications like pharmaceuticals and specialty fine chemicals. Process engineers have told us they favor this product in aqueous or mixed solvent systems, especially where sodium contaminants interfere with catalytic cycles or downstream purification.

    Manufacturers handling sensitive raw materials find potassium borohydride’s stability invaluable. Our product keeps well in sealed containers; exposure to ambient moisture drops off its reactivity only slowly, so minor delays in usage don’t spoil a batch. We design our packaging to discourage accidental hydration, making storage straightforward even in humid climates.

    Differences from Other Borohydrides

    Comparison with sodium borohydride brings this compound’s value into sharper focus. Sodium borohydride enjoys the broadest industrial use, but potassium borohydride shines where sodium’s reactivity is too aggressive or its by-products raise complications. In our own reduction pilot trials, potassium borohydride minimizes foaming and slurries that can complicate continuous operations. Teams replacing sodium-based reagents have shared with us their reduced need for process adjustments and less post-treatment cleanup, both of which save real operating time.

    Lithium borohydride, another member of the family, carries far higher reactivity but suffers from volatility, cost, and handling issues that make it unsuitable outside certain niche syntheses. We have tested side-by-side reductions using lithium, sodium, and potassium borohydrides in the context of specialty dye intermediates; potassium’s moderate strength offered the optimum balance, giving high selectivity without overdoing reductions or requiring specialized containment.

    For hydrogen generation applications, particularly in research into fuel cells and portable energy storage, market interest in potassium borohydride often rises. Researchers we supply mention the higher hydrogen release compared to sodium borohydride under similar conditions, and the less problematic residue for specific proton exchange membrane systems.

    Sample Applications Based on Direct Experience

    By controlling the feed rate and granule size, our production clients integrate potassium borohydride into continuous flow systems. One fine chemical manufacturer shared with us the measurable reduction in batch variability for a key pharmaceutical intermediate when they switched from sodium to potassium borohydride. The finer particle size made powder handling easier and reduced dusting, which minimized operator exposure and improved environmental compliance.

    In the field of metal finishing, potassium borohydride has proven useful for its even reduction of metal salts in electroless plating baths. Users reported more stable bath properties and a cleaner final deposit, with less tendency for unwanted side reactions. For those working at small scale, including research labs and development kitchens, our product delivers reproducibility without the need for complex stabilization systems or excessive buffering.

    Pool chemical suppliers once struggled with inconsistent reaction completeness using alternative hydrides. On consultation, our technical group helped them tune the amount and dissolution rate of our potassium borohydride to achieve better chlorine generation, leading to less unused raw material and lower treatment costs.

    Practical Storage and Handling

    Many reagents demand costly climate-controlled storage, but potassium borohydride’s ruggedness means customers can rely on standard dry containers, provided basic moisture control is observed. In practice, plant operators rarely need specialized PPE beyond what they use for related boron compounds, since the product generates no hazardous vapors under normal conditions. This ease-of-use improves productivity and keeps training requirements low for new staff.

    Routine inspection of storage areas and diligence in resealing containers after use are habits we recommend. Over years of shipment and field use, product stability has proven trustworthy so long as pallets remain undamaged and inner liners stay intact. In case a spill happens, cleanup is manageable with standard industrial vacuum systems, and no unusual corrosion or residue has been reported by the clients who document these events for us.

    Quality in Production: Internal Practice Drives Reliability

    Within our facility, implementation of batch controls and traceability for all raw materials allows us to call any customer back if future technical questions arise—though that is rare given the low incidence of product complaints. Our quality team checks every output lot using x-ray fluorescence for trace elements, as well as direct titration for active hydride content. As policy, no drum ships outside our plant gates without both electronic and physical test verification on record. Direct data from production helps us to improve and spot emerging issues before they become problems for the downstream customer.

    Our engineers conduct small-batch simulations whenever a major change in raw boron or potassium source enters the supply chain. This prevents erratic behavior in the field, such as observed color changes in waste effluent or inconsistent reactivity during transitional production runs.

    Safety Experience and Common Pitfalls

    Over the years, we’ve learned some of the finer points of safe handling by troubleshooting with plant chemists and safety officers in high-volume customers. Potassium borohydride, like all strong reducers, needs respect in terms of dust control and mixing rates; rushing an addition often results in foaming or local hot spots, which can disrupt carefully balanced reaction systems. As a practice, operators benefit from moderate agitation and staged addition to tap the full potential of the product while limiting spillage or uncontrolled heat generation.

    Reports from field users remind us that even experienced crews sometimes underappreciate how quickly local moisture in feed lines can trigger premature hydrolysis. Our ongoing advice is to thoroughly dribble dry product into solution with steady stirring, using cold water as the base solvent wherever possible; this keeps thermal spikes down and sustains higher yields on large-scale workups.

    Disposal, though straightforward compared to organic hydrides, requires careful monitoring to prevent uncontrolled hydrogen release. We focus on user education, offering guidance on safe neutralization and scaling waste-water treatment to keep all releases predictable and manageable. In regional audits with downstream partners, we have seen no recurrence of issues when our procedures are followed.

    Environmental Considerations and Waste Management

    Potassium borohydride reductions generate borate waste as a matter of chemistry, and our team has worked closely with customers to minimize environmental footprint. Customers moving towards circular economies appreciate our technical notes on capturing borates for use as micronutrients or in industrial glass manufacture. In several documented case studies, waste borate streams fed directly into closed-loop processes, lowering overall disposal costs and providing a feedstock for unrelated production lines.

    We have observed that, compared to lithium hydrides or organic hydrides, the environmental impact of borohydride residues registers much lower. Operating under local discharge permits, our facility has not triggered regulatory scrutiny for borate or potassium ion waste. We provide downstream users with guidelines tailored to local compliance frameworks, streamlining the paperwork associated with environmental reports.

    For those seeking greener processes, we encourage regular review of water use and trace contaminant removal after using potassium borohydride. Collaboration between our technical sales staff and client EHS coordinators leads to continuous improvement in water treatment and borate recovery, always aimed at keeping total costs down while satisfying both internal and public environmental demands.

    Market Trends and Future Directions Based on First-Hand Involvement

    The global trend towards safer, cost-effective reduction processes has brought renewed interest in potassium borohydride. Demand has ticked up, not just among established pharmaceutical manufacturers but also in R&D-focused organizations seeking new approaches in battery chemistry and specialty coatings. Our sales team has witnessed a steady shift from sodium hydride-based methods to controlled borohydride reductions, particularly as stricter safety requirements and insurance costs reshape industrial planning.

    Ongoing research in hydrogen energy storage keeps potassium borohydride on the radar. Several university partnerships have tested our product for its controlled hydrogen evolution rate and manageable byproducts. A few early adopters in the portable power sector cited the product’s shelf life and manageable safety profile as key reasons they chose our batches for their feasibility studies.

    Smaller chemical operations look for reliable supply chains. By maintaining in-house synthesis, quality control, and logistics, we stand as a direct resource for questions on formulation and long-term storage. Feedback collected by our support team often leads to practical modifications—be it finer custom granules, enhanced blending capabilities, or custom packaging for special regulatory markets.

    The field advances as knowledge gets shared. We continue to invest in application workshops, webinars, and technical bulletins, based directly on the recurring challenges and process improvements observed by our users. It’s a two-way street: we learn as much from our customers’ creative adaptations as they do from our internal technical developments.

    Why Potassium Borohydride Remains a Smart Choice

    Many seasoned plant operators see potassium borohydride as a tool that offers tangible reliability, workable safety margins, and controlled performance across reduction reactions. Its niche sits at the intersection of manageable reactivity and long-term shelf stability, qualities that become even more valuable as production costs and safety regulations tighten. In cases where sodium, lithium, or calcium hydrides have introduced headaches—whether by overly rapid reaction, tricky waste management, or difficult separation steps—potassium borohydride provides a middle ground that supports both R&D agility and steady, repeatable manufacturing.

    One of our core beliefs centers on open technical support. We don’t just supply bags of powder; we build lasting channels of knowledge, troubleshooting with users on everything from solvent compatibility to reaction energetics, to help them take smart risks and drive innovation in their product lines. In return, they keep us grounded—every real-world reaction pushes us to keep refining our own processes, testing new add-on services, or adapting packaging for easier access during critical production windows.

    The future for potassium borohydride looks promising. As an ingredient in high-value, precise reduction chemistry, it has proven itself to us and to hundreds of partners. Reliability comes from lived experience: batches that arrive on time, deliver promised purity, and perform as expected no matter the complexity of the task. Our approach means every shipment reflects years of know-how, a commitment to practical problem solving, and feedback directly from the hands that turn powder into finished goods every day.